The effects of vibration field on crystal structures and orientation of isotactic polypropylene injection samples

摘要

In this study, isotactic polypropylene (iPP) samples were prepared by self-made pressure vibration injection device, in which a periodical shear field was imposed on the iPP melt during the filling and packing stages. The crystal structures and orientation of samples were investigated by wide-angle X-ray diffraction and polarizing light microscopy (PLM). The β form and γ form were found in vibration injection molding samples. Compared with the static samples, the orientation of iPP chains within lamellae was observed in the transition layer (at the depth of 1.5 mm from the surface) of the vibration injection molding samples, and the orientation was found even in the core layer. The PLM observation indicates the β form exists in the transition and core region of the vibration sample. Besides, two types of β-PP could be observed simultaneously in the core region under high magnification. The bright β crystallites (βIII) are fan-shaped and lie perpendicularly to the flow direction. In the other hand, the ringed β crystallites (βIV) almost remain their spherulite shape. Moreover, fiber crystal was observed in vibration sample, even in the core region. Some fiber crystals in the transition region reappeared in the cooling circle after the sample was held at 180 °C for 2 min. This could be explained in structure memory effect and its high thermal stability.