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Photocatalytic Decomposition of Air Pollutants Using Electrodeposited Photocatalysts on Stainless Steel

机译:不锈钢上电沉积光催化剂对空气污染物的光催化分解

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The aim of our research was to develop an immobilization method for photocatalysts that is an alternative to the sol-gel or dip-coating methods and can be simply scaled up for technical applications. The investigated photocatalyst was TiO2, which was electrochemically deposited onto a cathode made of stainless steel. This deposited film was photocatalytically active. In order to enhance the photoactivity of the TiO2 film, commercially available P25 photocatalyst nanoparticles were occluded into the film. The effect of deposition current density as well as the amount of occluded nanoparticles on the photocatalytic activity and photoelectrochemical behavior was investigated. The photocatalytic activity was evaluated in a UV-LED reactor. The decomposition rate of toluene and cyclohexane in air was examined for all prepared stainless steel-photocatalyst composites. It was observed that deposits prepared with 5 g dm(-3) of P25 in the deposition bath showed the best photocatalytic activity and highest photocurrent.
机译:我们研究的目的是开发一种光催化剂的固定化方法,该方法可以替代溶胶-凝胶法或浸涂法,并且可以轻松地扩大规模以用于技术应用。研究的光催化剂是TiO2,它被电化学沉积在不锈钢制成的阴极上。该沉积膜具有光催化活性。为了增强TiO 2膜的光活性,将可商购的P25光催化剂纳米颗粒吸留到膜中。研究了沉积电流密度以及被吸附的纳米颗粒的数量对光催化活性和光电化学行为的影响。在UV-LED反应器中评估光催化活性。对于所有制备的不锈钢-光催化剂复合材料,检查了甲苯和环己烷在空气中的分解速率。观察到在沉积浴中用5 g dm(-3)P25制备的沉积物显示出最佳的光催化活性和最高的光电流。

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