Melt compounding of rigid PVC formulations with hydrotalcites

摘要

Hydrotalcites, compounds of magnesium-aluminium-hydroxycarbonate, are promoted as environmentally safe materials for costabilisation of PVC products. Commercial grades of hydrotalcites have been added to rigid PVC formulations, containing a range of different stabiliser types, to evaluate their contribution to heat stability and their effect on mechanical properties. Hydrotalcites are confirmed to be effective costabilisers for rigid PVC: static thermal stability (through oven testing) and dynamic thermal stability (via torque rheometry) of PVC compounds are modified by their presence. The extent of change is determined by the primary stabiliser type and the grade of the hydrotalcite. Detailed analysis of mechanical properties has been carried out on compression moulded samples and on extruded compounds. With the former, no significant change in tensile or impact performance was observed, for hydrotalcite levels up to 5 phr. Charpy impact data on extruded PVC have shown significant increase in performance of compounds containing an acrylate modifier when hydrotalcites are used.