Dielectric relaxation study of glycine-water mixtures using time domain reflectometry technique

摘要

The complex permittivity of glycine in water mixture for various temperatures and concentrations have been measured as a function of frequency between 10 MHz and 30 GHz using time domain reflectometry technique. Dielectric parameters, i.e. static dielectric constant and relaxation time were obtained from the complex permittivity spectra using nonlinear least square fit method. The dielectric relaxation parameter increases with an increase in molar concentration of glycine due to the formation of hydrogen bond groups by glycine molecule in an aqueous solution medium. The activation entropy, activation enthalpy and Kirkwood correlation factor have also been determined for glycine-water mixtures.View full textDownload full textKeywordsdielectric study, glycine, TDR techniqueRelated var addthis_config = { ui_cobrand: "Taylor & Francis Online", services_compact: "citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,more", pubid: "ra-4dff56cd6bb1830b" }; Add to shortlist Link Permalink http://dx.doi.org/10.1080/00319104.2010.551345