Band-structure parameters and Fermi resonances of exciton-polaritons in CsI and CsBr under hydrostatic pressure

摘要

Most alkali halides crystallize in the fcc sodium chloride structure. In contrast, with the exception of CsF, the Cs-halides form the simple cubic cesium chloride (CsCl) structure at ambient conditions and they have a substantially different electronic structure than other alkali halides; in particular, they have several nearly degenerate electronic levels near the Brillouin zone center. Highly resolved three-photon spectroscopy (TPS) measurements allow direct observation of the near band edge structure and, in the case of CsI, probe more states than one-photon techniques. A number of interesting phenomena, among them level repulsion (Fermi resonance), occur as these levels are tuned through one another by application of hydrostatic pressure. Doubling the photon energy range compared to a previous publication [see Yoo et al., Phys. Rev. Lett 84, 3875 (2000)] allows direct observation of the n=1, 2, and 3 exciton-polariton members of the Γ_8~--Γ_6~+ transition in CsI and lets us establish unambiguous values for the band gap (6.135 eV), binding energy (0.263 eV), and their pressure dependence up to 7 kbar. Similarly to CsI, the CsBr linewidth of the lowest Γ_4~- polariton (A) decreases upon compression and its bandgap must be higher than 7.20 eV.