We demonstrate that, by changing the direction of the chirp in vacuum-ultraviolet pulses, one can switch between excitation and ionization with very high contrast, if the carrier frequency of the light is resonant with two bound states. This is a surprising consequence of rapid adiabatic passage if extended to include transitions to the continuum. The chirp phase locks the linear combination of the two resonantly coupled bound states whose ionization amplitudes interfere constructively or destructively depending on the chirp direction under suitable conditions. We derive the phenomenon in a minimal model and verify the effect with calculations for helium as a realistic example.
展开▼
