Hydroaminations of unactivated alkenes with basic alkylamines: group 4 metal halide catalysts and Bronsted-acid organocatalysts

Lutz Ackermann; Ludwig T. Kaspar; Andreas Althammer

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Hydroaminations of unactivated alkenes with basic alkylamines: group 4 metal halide catalysts and Bronsted-acid organocatalysts

机译：未活化烯烃与碱性烷基胺的氨化反应：第4组金属卤化物催化剂和布朗斯台德酸有机催化剂

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摘要

Two distinct economical catalysts for intramolecular hydroaminations of electronically unactivated alkenes with basic amines are described, which are based on (a) group 4 metal halides under basic reaction conditions or (b) Bronsted-acid organocatalysts.

机译：描述了两种用于电子未活化烯烃与碱性胺的分子内加氢胺化的独特的经济催化剂，其基于（a）在碱性反应条件下的第4族金属卤化物或（b）布朗斯台德酸有机催化剂。

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来源
《Organic & biomolecular chemistry》 |2007年第12期|p.1975-1978|共4页
作者
Lutz Ackermann; Ludwig T. Kaspar; Andreas Althammer;
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作者单位

Institut fuer Organische und Biomolekulare Chemie, Georg-August- Universitaet, Tammannstr. 2, 37077, Goettingen, Germany;

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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
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机译：有机催化剂和过渡金属催化剂催化的未活化烯烃的级联碳羰基化：空气中芳烃中γ-二酮和γ-羰基醛的简便方法
2. Transition metal-free and base-mediated transformation arylation of unactivated benzene with aryl halides in presence of N,N '-bis(salicylidene) ethylenediamine as organocatalyst [J] . Ghonchepour Ehsan, Islami Mohammad Reza, Mostafavi Hamid, Catalysis Communications . 2018,第期

机译：在N，N'-BIS（水杨烯）乙二胺作为有机催化剂存在下，将无催化苯与芳基卤化物的无致活化苯的转化苯
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机译：在N，N'-BIS（水杨烯）乙二胺作为有机催化剂存在下，无催化苯的无催化苯的无致活化苯的转化芳族
4. Augmenting Basicity and Nucleophilicity by Smart Combination of Electronic Effects: Strong Metal-Free Bases and New Zwitterionic Organocatalysts. [C] . Ilya M. Lyapkalo, Anastasia A. Grishina, Roman A. Kunetskiy European Symposium on Organic Chemistry . 2009

机译：通过电子效应的智能组合增强碱性和亲核性：强型无金属基质和新的两性离子有机催化剂。
5. Binaphtholate and Octahydrobinaphtholate Rare-Earth Metal Catalysts for Asymmetric Hydroamination of Alkenes [D] . Nguyen, Hiep Nhu. 2018

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6. Desymmetrization of unactivated bis-alkenes via chiral Brønsted acid-catalysed hydroamination [O] . Zhang-Long Yu, Yong-Feng Cheng, Na-Chuan Jiang, 2020

机译：通过手性Brønsted酸性催化的水醋酸酸催化的酸催化剂去对称化
7. Iron-Based Catalyst for Borylation of Unactivated Alkyl Halides without Using Highly Basic Organometallic Reagents [O] . -1

机译：用于不使用高碱性有机金属试剂的未活化烷基卤化物的铁基催化剂

Hydroaminations of unactivated alkenes with basic alkylamines: group 4 metal halide catalysts and Bronsted-acid organocatalysts

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