A concerted mechanism for uncatalysed transfer of carbon substituents from diimides to C=C and C≡C

Jorn B. Christensen; Lars Henriksen; Theis I. Soiling

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A concerted mechanism for uncatalysed transfer of carbon substituents from diimides to C=C and C≡C

机译：碳取代基从二酰亚胺到C = C和C≡C的未催化转移的协同机制

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We present high-level computational predictions regarding a novel uncatalysed, yet feasible, C-C bond forming reaction.The reduction of alkenes or alkynes with cis-diimide is a remarkable reaction in the sense that hydrogen is transferred to a carbon-carb

机译：我们提供了关于新型未催化但可行的C-C键形成反应的高级计算预测。从氢转移到碳-碳氢化合物的意义上讲，顺式-二亚胺还原烯烃或炔烃是一个了不起的反应

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《Organic & biomolecular chemistry 》 |2008年第3期| 440-442| 共3页
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Jorn B. Christensen; Lars Henriksen; Theis I. Soiling;
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A concerted mechanism for uncatalysed transfer of carbon substituents from diimides to C=C and C≡C

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