First kinetic evidence for the CH/π and n solute-solvent interaction of C_(60) in the Diels-Alder reaction with cyclohexadiene

Takumi Oshima; Tsubasa Mikie; Naohiko Ikuma; Hajime Yakuma

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First kinetic evidence for the CH/π and n solute-solvent interaction of C_(60) in the Diels-Alder reaction with cyclohexadiene

机译：C_（60）在Diels-Alder与环己二烯反应中CH /π和n / n溶质-溶剂相互作用的第一个动力学证据

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The first CH/π solute-solvent interaction of C_(60) was evidenced by the kinetic solvent effects in the Diels-Alder reaction with 1,3-cyclohexadiene based on the evaluation of linear free energy relationship of log k_2 with empirical solvent polarity and basicity parameters, E_T(30) and D_π, respectively.

机译：C_（60）的第一个CH /π溶质-溶剂相互作用通过对log k_2的线性自由能关系与经验溶剂极性和线性关系的评估，通过与1,3-环己二烯的Diels-Alder反应中的动力学溶剂效应证明。基本性参数分别为E_T（30）和D_π。

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《Organic & biomolecular chemistry》 |2012年第9期|p.1730-1734|共5页
作者
Takumi Oshima; Tsubasa Mikie; Naohiko Ikuma; Hajime Yakuma;
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Departamento de Quimica Orgdnica Universidad de Murcia Campus de Espinardo, 30100 Murcia, Spain;

Departamento de Quimica Orgdnica Universidad de Murcia Campus de Espinardo, 30100 Murcia, Spain;

Departamento de Nanociencia Molecular y Materiales Orgdnicos, Instituto de Ciencia de Materiales de Barcelona (CSIC), Campus U.A.B., 08193 Bellaterra, Spain;

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2. Experimental Evidence of Specific Solute-Solvent Interactions of Fullerences C_(60) and C_(70) in Solution: One-Dimensional Steady-State Intermolecular ~(13)C, ~1H Overhauser Effect Study [J] . Anastasios Troganis, Ioannis P. Gerothanassis, Demetrios K. Papademitriou Journal of magnetic resonance . 1998,第1期

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3. Kinetics and regioselectivity in the Diels-Alder reaction of fulleroids vs. Methanofullerene and C_(60) [J] . Naohiko Ikuma, Yasunori Susami, Takumi Oshima Organic & biomolecular chemistry . 2010,第6期

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First kinetic evidence for the CH/π and n solute-solvent interaction of C_(60) in the Diels-Alder reaction with cyclohexadiene

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