Internal elemental imaging by scanning X-ray fluorescence microtomography at the hard X-ray microprobe beamline of the SSRF: Preliminary experimental results

摘要

Synchrotron-based X-ray micro-fluorescence (μ-SXRF) is a non-destructive analytical technique and has been widely used to detect and quantify the elemental composition of samples in their natural state. To determine the internal elemental distributions within samples, X-ray fluorescence microtomography has been developed based on the hard X-ray microprobe at beamline BL15U1 of the Shanghai Synchrotron Radiation Facility (SSRF) in Shanghai, China. This technique was applied to image the cross-sectional distributions of multiple elements within a single human hair, and its validity was evaluated by comparing the results with the elemental maps of a thin hair section obtained using the well-established μ-SXRF mapping method. Elemental images of S, Ca, Mn, Fe, Cu, and Zn within a virtual slice of the hair were reconstructed after the tomographic measurements. The tomographic images of heavy elements like Fe, Cu, and Zn were found to be in good agreement with the corresponding u-SXRF maps. Light elements, such as S, however, represented different patterns due to non-negligible self-absorption in the sample, and sophisticated correction algorithms accounting for such effects are required for obtaining qualitatively and quantitatively more accurate images. Compared to μ-SXRF mapping, X-ray fluorescence microtomography reduces the sample preparation requirements and has been demonstrated in this work as being a more ideal and effective imaging modality to non-destructively mapping out the internal distribution of heavy elements within samples at the micrometer scale at the SSRF.