Investigation of the interaction of copper(Ⅱ) oxide and electron beam irradiation crosslinkable polyethylene

摘要

In this study, the effects of electron beam irradiation on the properties of copper(Ⅱ) oxide when added to low-density polyethylene (LDPE) blends were investigated. It was found that the addition of low loading level of copper(Ⅱ) oxide (≤ 2 phr) to LDPE results in significantly poorer gel content and hot set results. However, the incorporation of higher loading level of copper(Ⅱ) oxide (≥ 3 phr) could slightly increase the degree of crosslinking in all irradiated LDPE composites. This is due to the fact that higher amounts of copper(Ⅱ) oxide could slightly induce the formation of free radicals in LDPE matrix. Besides, increasing irradiation doses was also found to gradually increase the gel content of LDPE composites by generating higher amounts of free radicals. As a consequence, these higher amounts of free radicals released in the LDPE matrix could significantly increase the degree of crosslinking. The addition of copper(Ⅱ) oxide could reduce the tensile strength and fracture strain (elongation at break) of LDPE composites because of poorer interfacial adhesion effect between copper(Ⅱ) oxide particles and LDPE matrix. Meanwhile, increasing irradiation doses on all copper(Ⅱ) oxide added LDPE composites could marginally increase the tensile strength. In addition, increasing irradiation dose could enhance the thermal stability of LDPE composites by increasing the decomposition temperature. The oxidation induction time (OIT) analysis showed that, because of the crosslinking network in the copper(Ⅱ) oxide added LDPE composites, oxidation reaction is much delayed.