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A new potential paper resource; recyclability of paper cups coated with water-soluble polyacrylate-based polymer

机译:新的潜在纸张资源;水溶性聚丙烯酸酯基聚合物涂层纸杯的可回收性

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摘要

Paper cups are typically made by laminating PE or PLA onto the surface of paper. PE and PLA are hydrophobic and easy for film formation. However, recycling of PE- or PLA-coated paper cups is difficult. Polyacrylate (PA)-based polymers may be an alternative to PE and PLA, and recycling of polyacrylate-coated paper cups may be considered if the barrier film can be disintegrated. The recyclability of paper cups coated with PE-, PLA-, and PA-based polymers was investigated by pilot pulper and screen. Furthermore, mechanical treatments were investigated for the removal of remaining polyacrylate flakes (RPF). The pulping yield of PA-coated paper cups was higher than that of PE-or PLA-coated paper cups, since PE or PLA films were discarded as hole screen rejects. In the case of PA-coated paper cups, RPF could not be separated by slot screening due to its deformability. However, RPF must be treated properly since it can result in specks on the surface of paper. RPF could be fragmented effectively, with over 95 % disappearing after one pass of kneading and 10 min of beating. Consequently, it may be possible to use PA-coated paper cups as a raw material in the paper recycling process.
机译:纸杯通常是通过将PE或PLA层压到纸张表面上制成的。 PE和PLA具有疏水性,易于成膜。但是,很难回收PE涂层或PLA涂层的纸杯。基于聚丙烯酸酯(PA)的聚合物可能是PE和PLA的替代品,如果可以分解阻挡膜,则可以考虑回收聚丙烯酸酯涂层纸杯。通过中试碎浆机和筛分机研究了涂有PE-,PLA-和PA-基聚合物的纸杯的可回收性。此外,研究了机械处理以去除残留的聚丙烯酸酯薄片(RPF)。 PA涂层纸杯的制浆产量高于PE或PLA涂层纸杯的制浆产量,因为将PE或PLA薄膜作为孔筛筛渣丢弃了。在使用PA涂层的纸杯的情况下,RPF由于其可变形性而无法通过狭缝筛分分离。但是,必须正确处理RPF,因为它可能导致纸张表面出现斑点。 RPF可以有效地破碎,经过一遍揉搓和10分钟打浆后,超过95%的RPF消失了。因此,有可能在纸张回收过程中使用涂有PA的纸杯作为原材料。

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