Determination of trace vanadium in soil by cloud point extraction and graphite furnace atomic absorption spectroscopy

摘要

This work describes a new analytical procedure for trace vanadium by graphite furnace atomic absorption spectroscopy coupled to cloud point extraction (CPE) as the separation-preconcentration method. The CPE behavior of vanadium using methylene blue as complex agent and Triton X-100 as a surfactant was investigated systematically. Under the optimized conditions, the detection limit was 0.7 ng · mL−1, and the relative standard deviation was 4.3% for vanadium (c = 50.0 ng · mL−1, n = 5). The recovery of vanadium was in the range of 98.9–102.8%. The method was applied to the analysis of vanadium in certified reference materials and real samples. The results obtained were in good agreement with the certified values.