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In Situ Synthesis and Characterization of Shape Memory Alloy Nitinol by Laser Direct Deposition

机译:激光直接沉积原位合成形状记忆合金镍钛诺及其表征

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摘要

Nitinol is well known for its unique shape-memory and super-elastic properties along with its excellent biomechanical compatibility and corrosion resistance. In this study, a laser direct deposition technique was explored to synthesize high-quality, near-net-shape nitinol components directly from elemental nickel and titanium powders as opposed to using expensive prealloyed nitinol powder. The systematic characterization of samples was done using X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). Transformation temperatures were obtained using differential scanning calorimetry (DSC). With an optimum ratio of nickel and titanium powder mixture, optimal laser parameters, and post-heat treatment, samples with homogeneous and nearly fully dense NiTi phase were synthesized with less unwanted secondary phases occupying less than 3.2 pct volume fraction. Furthermore, these results were compared with those obtained for samples deposited using prealloyed nitinol powder. This technique offers maximum flexibility and cost benefit in the manufacturability of near-net-shape nitinol components.
机译:镍钛诺以其独特的形状记忆和超弹性特性以及出色的生物力学相容性和耐腐蚀性而闻名。在这项研究中,探索了一种激光直接沉积技术,以直接从元素镍和钛粉中合成高质量,接近最终形状的镍钛合金成分,而不是使用昂贵的预合金镍钛合金粉。使用X射线衍射(XRD),扫描电子显微镜(SEM)和能量色散X射线光谱(EDS)对样品进行系统表征。使用差示扫描量热法(DSC)获得转变温度。利用最佳的镍和钛粉末混合物比例,最佳的激光参数以及后热处理,可以合成出具有均匀且几乎完全稠密的NiTi相的样品,较少的次要相占体积分数的比例小于3.2 pct。此外,将这些结果与使用预合金镍钛诺粉末沉积的样品获得的结果进行了比较。该技术在制造接近最终形状的镍钛合金组件时提供了最大的灵活性和成本优势。

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