Influence of the Organic Additions on Structure, Corrosion Resistance and Tribological Properties of Ni/AI_2O_3 Composite Coatings

摘要

Composite Ni/Al_2O_3 coatings were electrochemically deposited from a Watts bath modified with the organic additions of dioctyl sulphosuccinate sodium salt C_(20)H_(37)NaO_7S-(DSS) and 2,3-dihydroxy-l,2 benzisothiazol-3-one 1,1-dioxide C_7H_5NO_3-(LSA). The effect of different amount (50 and 100 g/l) of A1_2O_3 powder and organic additions on microstructure, microhardness, corrosion resistance and tribological properties was investigated. The coatings were examined by optical microscopy, scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX) and X-ray diffraction (XRD) techniques. The electrochemical behaviour of the coatings in corrosive solutions (1 M NaCl and 1 M Na_2SO_4) was investigated by potentiodynamic polarisation. The tribological properties were investigated by the Taber abrasive wear test, a standard test often applied in industrial practice. The results show that Al_2O_3 particles are uniformly distributed in the composite coatings compared with coatings without organic additions. The addition of organic compounds also reduced the size of the forming nickel crystallites and improved the tribological and corrosion properties of coatings contalning the dispersed hard particles of Al_2O_3 added in an amount of 50 g/l and the addition of organic LSA and DSS compounds.