Processing and characterization of a carbon black-filled electrically conductive Nylon-12 nanocomposite produced by selective laser sintering

摘要

Selective laser sintering (SLS), a layered manufacturing technique was explored to process an electrically conductive polymer nanocomposite made of Nylon-12 reinforced with 4wt% of carbon black. SLS process parameters were optimized in order to maximize the flexural modulus. The porosity and morphology were studied using optical microscopy and scanning electron microscopy (SEM). The crystalline state was characterized using differential scanning calorimetry (DSC) and X-ray diffraction (XRD). The electrical conductivity was determined using the four probe technique. Results indicate that carbon black-filled Nylon-12 nanocomposites can be successfully made by SLS. Maximum flexural modulus values of 1750 MPa and 1450 MPa were achieved for the neat polymer and the nanocomposite, respectively. A reduction in the flexural modulus of the nanocomposite is likely due to the formation of a segregated structure in the nanocomposite and a weak polymer-filler interface. The optimized neat polymer and the nanocomposites had average densities of around 97% and 96% relative to full density, respectively. The electrical conductivity of the nanocomposite was approximately 1 × 10~(-4) S/cm, which is five orders of magnitude higher than that of the neat polymer processed by SLS, and indicates that the onset of percolation behavior occurs below the 4wt% loading of carbon black.