The role of SiO2 nanoparticles and ground granulated blast furnace slag admixtures on physical, thermal and mechanical properties of self compacting concrete

摘要

In this work, strength assessments and percentage of water absorption of self compacting concrete containing ground granulated blast furnace slag and SiO_2 nanoparticles as binder have been investigated. Portland cement was replaced by different amounts of ground granulated blast furnace slag and the properties of concrete specimens were investigated. Although it negatively impacts the physical and mechanical properties of concrete at early ages of curing, ground granulated blast furnace slag was found to improve the physical and mechanical properties of concrete up to 45 wt% at later ages. SiO_2 nanoparticles with the average particle size of 15 nm were added partially to concrete with the optimum content of ground granulated blast furnace slag and physical and mechanical properties of the specimens were measured. SiO_2 nanoparticle as a partial replacement of cement up to 3.0 wt% could accelerate C-S-H gel formation as a result of increased crystalline Ca(OH)2 amount at the early ages and hence increase strength and improve the resistance to water permeability of concrete specimens. The increased SiO_2 nanoparticles' content by more than 3.0wt%, causes the reduced strength because of the decreased crystalline Ca(OH)_2 content required for C-S-H gel formation. Several empirical relationships have been presented to predict flexural and split tensile strength of the specimens by means of the corresponding compressive strength at a certain age of curing. Accelerated peak appearance in conduction calorimetry tests, more weight loss in thermogravimetric analysis and more rapid appearance of the peaks related to hydrated products in X-ray diffraction results, all indicate that SiO_2 nanoparticles could improve mechanical and physical properties of the concrete specimens.