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Unstable interstitial-vacancy pairs and paradoxes of high temperature properties of metals

机译:金属的高温特性不稳定的间隙空位对和悖论

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There are some quite general and quite unex- pected features of the high temperature behaviour of metals being reviewed by Ya. Kraftmakher. These are the discrepancy between the estimated number of point de fects, determined by equilibrium and quenching experi ments, the discrepancy between a number of point de- fects, estimated by high temperature dilatometric mea- surements and heat capacity ones, as well as the pecu- liarities in changing the selfdiffusivity mechanisms at high temperatures. The mechanisms of these phenomena had been analysed, but some new qualitative and semi- quantitative approaches are here suggested for explain- ing the named paradoxes as the basis of a model of un- stable pairs vacancy-atom at interstice, being the third type of equilibrium point defects in solids, in addition to Frenkel 's and Shottkv 's defects.
机译:Ya正在审查金属的高温行为,其中有一些非常普遍且非常出乎意料的特征。 Kraftmakher。这些是通过平衡和淬火实验确定的估计点缺陷数量之间的差异,通过高温膨胀测量和热容测量估计的点缺陷数量之间的差异,以及-在高温下改变自扩​​散机制的责任。已经分析了这些现象的机理,但是在此建议一些新的定性和半定量方法来解释命名的悖论,以此作为间隙中不稳定原子对空位原子模型的基础,这是空穴的第三种类型。除Frenkel和Shottkv缺陷外,固体中的平衡点缺陷。

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