Effect of intercalated aromatic sulfonates on uptake of aromatic compounds from aqueous solutions by modified Mg-Al layered double hydroxide

摘要

In this study, we utilized Mg-Al layered double hydroxide (Mg-Al LDH) modified by intercalation with three aromatic sulfonates-2,7-naphthalene disulfonate (2,7-NDS~(2-)), benzenesulfonate (BS~-), and benzenedisulfonate (BDS~(2-))-for the uptake of two aromatics-1,3-dinitrobenzene (DNB) and anisole (AS)-from aqueous solution and determined the effect of the aromatic sulfonates on the uptake of these aromatics. We found that the electron-rich aromatic ring of the intercalated aromatic sulfonates such as 2,7-NDS~(2-) undergoes strong π-π stacking interactions with the electron-poorer benzene ring of DNB in aqueous solution, and these interactions result in a higher uptake of DNB by the modified Mg-Al LDHs. In contrast, the electron-poor aromatic ring of the aromatic sulfonates such as BDS~(2-) undergoes weak π-π stacking interactions with the electron-poorer benzene ring of DNB, and these interactions result in a lower uptake of DNB by the modified Mg-Al LDHs.