Facile preparation of nitrogen-doped porous carbon from waste tobacco by a simple pre-treatment process and their application in electrochemical capacitor and CO_2 capture

摘要

Preparing nitrogen-doped porous carbons directly from waste biomass has received considerable interest for the purpose of realizing the atomic economy. In this study, N-doped porous carbons have been successfully prepared from waste tobaccos (WT) by a simple pre-treatment process. The sample calcinated at 700 ℃ (WT-700) shows a micro/meso-porous structures with a BET surface area of 1104 m~2g~(-1) and a nitrogen content of ca. 19.08 wt.% (EDS). Performance studies demonstrate that WT-700 displays 170 F g~(-1) electrocapacitivity at a current density of 0.5 A g~(-1) (in 6M KOH), and a CO_2 capacity of 3.6 mmol g~(-1) at 0 ℃ and 1 bar, and a selectivity of ca. 32 for CO_2 over N_2 at 25 ℃. Our studies indicate that it is feasible to prepare N-enriched porous carbons from waste natural crops by a pretreatment process for potential industrial application.