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Electrospun Mesoporous W~(6+)-doped Tio_2 Thin Films For Efficient Visible-light Photocatalysis

机译:电纺中孔W〜(6+)掺杂Tio_2薄膜用于高效可见光催化

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Mesoporous W~(6+)-doped TiO_2 thin films photocatalysts were prepared via electrospinning and sol-gel chemistry, employing a triblock copolymer as structure-directing agent, and were characterized by SEM, TEM, XRD as well as N_2 adsoption/desorption isotherm. The photocatalytic activity of the films was investigated by employing the methylene blue (MB) as probe. In this study, 3% was the most suitable content of W~(6+) in TiO_2, at which the recombination of photoinduced electrons and holes could be effectively inhibited. In the mean time, making the photocatalysts at nanoscale and with mesopores in the films could produce more reactive sites to adsorbe and oxidize pollutants.
机译:以三嵌段共聚物为结构导向剂,通过静电纺丝和溶胶-凝胶化学制备了介孔的W〜(6+)掺杂TiO_2薄膜光催化剂,并通过SEM,TEM,XRD和N_2吸附/解吸等温线进行了表征。 。以亚甲基蓝(MB)为探针研究了膜的光催化活性。本研究中,最合适的TiO_2中W〜(6+)含量为3%,可有效抑制光致电子和空穴的复合。同时,将光催化剂制成纳米级且在膜中具有中孔可以产生更多的反应性位点以吸附和氧化污染物。

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