Synthesis and luminescent properties of ZnNb_2O_6 nanocrystals for solar cell

摘要

The phase formation, morphology and luminescent properties of ZnNb_2O_6 nanocrystals by the sol-gel method were investigated at a lower temperature than that of the traditional solid-state reaction method. The products were characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), photoluminescence spectroscopy (PL) and absorption spectra. The activation energy of ZnNb_2O_6 grain growth is obtained about 18.4 kJ/mol. The diameters of the nanocrystals are in the range of 20-40 nm. The PL spectra excited at 276 nm have a broad and strong blue emission band maximum at 450 nm, corresponding to the self-activated luminescence of the niobate octahedra group |NbO_6]~(7-). The optical absorption spectrum of the sample at a calcination temperature of 800 ℃ has a band gap energy of 3.68 eV.