Self-assembly of pyramid-like magnetites with hierarchical structures as lithium battery anode materials

摘要

Pyramid-like magnetite crystals are assembled via a simple one-pot hydrothermal process with industrialized environmental free raw materials. It is revealed that these crystals have hierarchical structures which are self-assembled of nano-sized ultrafine magnetite spheres. The electrochemical properties of the as-prepared magnetite are studied by galvanostatic cell cycling at different current rates. The electrodes exhibit high reversible specific capacity (about 1600 mA h g~(-1) at 40 mA g~(-1) ) at low rate and good cycle property at 1 C. The specific capacity increases after it reaches a minimum, which is believed to be related to the formation of SEI film. After cycled 500 times at 1 C, the reversible capacity is still higher than 340 mA h g~(-1).