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Facile strategy to construction Co_2P/g-C_3N_4 heterojunction with excellent photocatalytic water splitting activity

机译:构建CO_2P / G-C_3N_4异质结具有优异的光催化水分裂活动的策略

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The development of catalysts with excellent light harvest capacity and faster charge separation ability is required in order to improve the photocatalytic hydrogen evolution efficiency. In this work, Co2P/g-C3N4 was synthesized using red phosphorus as P sources by in-situ solvent-thermal method. The results showed that the best hydrogen evolution rate is 5916 mu mol.g (1.)h (1), which is about 39.4 times higher than that of pure g-C3N4. Furthermore, 1389 mu mol.g (1.)h (1) of the hydrogen evolution rate can be achieved under visible light. The excellent activity of the composite results from the Schottky junction effect and the enhanced surface reaction kinetics. This work reported a simple and effective photocatalyst about transition metal phosphides. (c) 2020 Elsevier B.V. All rights reserved.
机译:需要优异的光收获容量和更快的电荷分离能力的催化剂的发展,以提高光催化氢进化效率。在该作品中,通过原位溶剂热法使用红磷作为P来源合成CO 2P / G-C3N4。结果表明,最佳的氢进化速率为5916μmol.g(1),其比纯G-C3N4高约39.4倍。此外,在可见光下可以实现1389μmol.g(1)的氢进化速率。复合材料的优异活性来自肖特基结效应和增强的表面反应动力学。这项工作报告了关于过渡金属磷化物的简单且有效的光催化剂。 (c)2020 Elsevier B.v.保留所有权利。

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