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Facile One-Step Hydrothermal Fabrication of (Sr0.6Bi0.305)2Bi2O7/SnO2 Heterojunction with Excellent Photocatalytic Activity

机译:具有优异光催化活性的(Sr0.6Bi0.305)2Bi2O7 / SnO2异质结的一步式水热制备

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摘要

The pyrochlore-type (Sr Bi ) Bi O (SBO), containing Bi and Bi mixed valent states, was recently found to be used as a new visible light responsive photocatalyst. Novel SBO/SnO heterostructured composites were synthesized through a facile one-step hydrothermal method. The phase structure, morphology, chemical composition, and optical properties of the obtained samples were characterized by XRD, SEM, TEM, XPS, and UV-vis DRS. Compared to pure SBO and SnO , the synthesized SBO/SnO composites exhibited significantly enhanced photocatalytic efficiency. The results indicated that the photoinduced holes and superoxide radicals play a dominant role and are the main reactive species during the degradation of Methylene Blue (MB) solution under visible light irradiation. Heterojunctions, formed in samples, directly contribute to the improvement of photocatalytic efficiency of SBO/SnO composites, since it not only broadens the light response range, but also accelerates the separation of photogenerated carriers.
机译:最近发现,含有Bi和Bi混合价态的烧绿石型(Sr Bi)Bi O(SBO)被用作新的可见光响应型光催化剂。通过一种简便的一步水热法合成了新型SBO / SnO异质结构复合材料。通过XRD,SEM,TEM,XPS和UV-vis DRS对所得样品的相结构,形态,化学组成和光学性质进行了表征。与纯SBO和SnO相比,合成的SBO / SnO复合材料表现出显着提高的光催化效率。结果表明,在可见光照射下,亚甲基蓝溶液降解过程中,光诱导的空穴和超氧化物自由基起主要作用,是主要的反应物种。样品中形成的异质结,不仅增加了光响应范围,而且还加速了光生载流子的分离,直接有助于提高SBO / SnO复合材料的光催化效率。

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