The effect of N-doped quantum dots on the properties of in situ prepared colorless polyimide nanocomposite films

摘要

Conventional polyimide nanocomposites reinforced with graphene-based nanofillers usually possess excellent properties, such as high thermal decomposition temperature, enhanced tensile strength, tensile modulus, etc. However, the elongation at break of the nanocomposites is reduced. Here, we prepared N-doped graphene quantum dots/colorless polyimide nanocomposite (N-GQDs/CPI) films for the first time by in-situ polymerization, whose elongation at break is about 2 times that of the pure film. Meanwhile, the thermal properties and other mechanical properties of the films are improved. Through analyzing FT-IR, XPS, XRD, TAG SEM, etc. of N-GQDs and the films, we consider that the strengthening mechanism of matrix performance is attributed to N-GQDs' well dispersion, its small size effects and strong interface interaction with the matrix. Furthermore, at the indicative wavelength of 550 nm, the optical transmittance of the film with 1 wt% N-GQDs stillmaintains 79%, indicating the resulting films have excellent optical transmittance. The hydrophilic properties of the prepared films' surface is reduced, their water surface contact angle are increased from 63 +/- 2.7 degrees to 92 +/- 1.7 degrees with the content of N-GQDs increasing. This research shows that N-GQDs can enhance the various properties of polyimide and provides a high performance nanocomposite films for potential flexible substrates. (C) 2017 Elsevier Ltd. All rights reserved.