Novel Naproxen Derivatives: Lewis Acid/Transition-metal Free Synthesis via C-C Bond Forming Reaction

Sarbani Pal P. Bindu Pragnyadhar Reddy Venna P. K. Dubey

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Novel Naproxen Derivatives: Lewis Acid/Transition-metal Free Synthesis via C-C Bond Forming Reaction

机译：新型萘普生衍生物：路易斯酸/ C-C键形成反应的无过渡金属合成

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Naproxen or 2-(6-methoxy naphthalen-2-yl)propionic acid participated in trifluoroacetic anhydride/ phosphoric acid mediated C-C bond forming reaction in a regioselective fashion when treated with a variety of arene or heteroarene under a solvent-free condition affording novel 1-aryl/heteroaryl substituted 2-(6-methoxy naphthalen-2-yl)propan-1-ones in good yields.

机译：萘普生或2-（6-甲氧基萘-2-基）丙酸在无溶剂条件下用多种芳烃或杂芳烃处理时，以区域选择性方式参与了三氟乙酸酐/磷酸介导的CC键形成反应。 -芳基/杂芳基取代的2-（6-甲氧基萘-2-基）丙-1-酮具有良好的收率。

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来源
《Letters in Organic Chemistry》 |2007年第4期|p.292-295|共4页
作者
Sarbani Pal P. Bindu Pragnyadhar Reddy Venna P. K. Dubey;
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作者单位

Department of Chemistry, MNR Post Graduate College, Kukatpally, Hyderabad-500072, India.;

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正文语种 eng
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关键词
Naproxen, acylation, trifluoroacetic anhydride, phosphoric acid;

机译：萘普生;酰化;三氟乙酸酐;磷酸;

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专利

1. Novel naproxen derivatives: Lewis acid/transition-metal free synthesis via C-C bond forming reaction [J] . Pal S, Bindu P, Venna PR, Letters in organic chemistry . 2007,第4期

机译：新型萘普生衍生物：路易斯酸/ C-C键形成反应可自由合成过渡金属
2. Transition-metal/Lewis acid free synthesis of acyl benzothiophenes via C-C bond forming reaction [J] . Sarbani Pal, Mohammad Ashrafuddin Khan, P Bindu, Beilstein journal of organic chemistry. . 2007,第1期

机译：通过C-C键形成反应的无过渡金属/路易斯酸的酰基苯并噻吩的合成
3. Transition-metal-free C-C bond forming reactions of aryl, alkenyl and alkynylboronic acids and their derivatives [J] . Roscales S., Csaky A. G. Chemical Society Reviews . 2014,第24期

机译：芳基，烯基和炔基硼酸及其衍生物的无过渡金属C-C键形成反应
4. A Ruthenium-Catalyzed Reaction of Aromatic Ketones with Organoboronic Acid Esters:A New Method for C-C Bond Formation via C-H Bonds Cleavage [C] . Fumitoshi Kakiuchi, Shintaro Kan, Kimitaka Igi, Symposium on Organometallic Chemistry . 2003

机译：芳香酮与有机硼酸酯的芳香酮催化反应：通过C-H键切割的C-C键形成新方法
5. Harnessing Cyclic Alkynes for the Synthesis of Heterocyclic Compounds and Nickel-Catalyzed C-C Bond Forming Reactions From Amide Derivatives. [D] . Medina, Jose Miguel. 2017

机译：利用环状炔烃合成杂环化合物和酰胺衍生物镍催化的C-C键形成反应。
6. Transition-metal/Lewis acid free synthesis of acyl benzothiophenes via C-C bond forming reaction [O] . Sarbani Pal, Mohammad Ashrafuddin Khan, P Bindu, 2007

机译：通过C-C键形成反应的过渡金属/路易斯酸无规合成酰基苯并噻吩
7. Transition-metal/Lewis acid free synthesis of acyl benzothiophenes via C-C bond forming reaction [O] . Pal, Sarbani, Khan, Mohammad Ashrafuddin, Bindu, P, 2007

机译：通过C-C键形成反应的过渡金属/路易斯酸无规合成酰基苯并噻吩

Novel Naproxen Derivatives: Lewis Acid/Transition-metal Free Synthesis via C-C Bond Forming Reaction

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