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Kinetics of adsorption of pharmaceutical substances from aqueous solutions on activated carbons

机译:活性炭从水溶液中吸附药物的动力学

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The article has investigated regularities of adsorption of sulfanilamide, sulfathiazole, procaine, levamisole and caffeine on activated carbons of various porous structure. The adsorption rate of substances diminishes in the series sulfanilamide > caffeine > procaine > sulfathiazole > levamisole and decreases with an increase of the fraction of micropores in the structure of sorbents. It was found that at the degree of using the adsorption capacity of the sorbent of up to gamma = 0.5-0.6 the kinetics of adsorption satisfactorily is described by means of an external diffusion model. The use of 50% of sorption capacity of activated carbon is achieved over similar to 10% time necessary for establishing adsorption equilibrium.
机译:本文研究了磺胺,磺胺噻唑,普鲁卡因,左旋咪唑和咖啡因在各种多孔结构的活性炭上的吸附规律。在磺胺>咖啡因>普鲁卡因>硫代噻唑>左旋咪唑系列中,物质的吸附速率降低,并随着吸附剂结构中微孔分数的增加而降低。已经发现,在利用吸附剂的吸附能力高达γ= 0.5-0.6的程度下,通过外部扩散模型令人满意地描述了吸附动力学。在建立吸附平衡所需的10%的时间内,使用了活性炭50%的吸附容量。

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