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首页> 外文期刊>Journal of the American Chemical Society >A Reinterpretation of the Mechanism of the Simplest Reaction at an sp~3-Hybridized Carbon Atom:H + CD_4-CD_3 + HD
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A Reinterpretation of the Mechanism of the Simplest Reaction at an sp~3-Hybridized Carbon Atom:H + CD_4-CD_3 + HD

机译：重新解释sp〜3-杂化碳原子上最简单反应的机理：H + CD_4-CD_3 + HD

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摘要

The H + CD4 reaction is the prototypical abstraction reaction occurring at an sp~3-hybridized carbon atom.It also plays a role in combustion chemistry and has features that distinguish it from well understood triatomic reactions.Furthermore,as the simplest six-atom system,it has served as a testing ground for new theoretical methods.
机译：H + CD4反应是发生在sp〜3杂化碳原子上的原型抽象反应。它在燃烧化学中也起着一定作用，并且具有与众所周知的三原子反应区分开的特征。此外，它是最简单的六原子系统，它已成为新理论方法的试验场。

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  • 来源
    《Journal of the American Chemical Society》 |2005年第34期|p.11898-11899|共2页
  • 作者

    Jon P.Camden; Hans A.Bechtel; Davida J.Ankeny Brown; Marion R.Martin; Richard N.Zare; Wenfang Hu; Gyorgy Lendvay; Diego Troya; George C.Schatz;

  • 作者单位

    Department of Chemistry,Stanford University,Stanford,California 94305-5080,Department of Chemistry,Northwestern University,Evanston,Illinois 60208-3113,Chemical Research Center,Hungarian Academy of Sciences,P.O.Box 17,H-l525 Budapest,Hungary,and Depa;

    Department of Chemistry,Stanford University,Stanford,California 94305-5080,Department of Chemistry,Northwestern University,Evanston,Illinois 60208-3113,Chemical Research Center,Hungarian Academy of Sciences,P.O.Box 17,H-l525 Budapest,Hungary,and Depa;

    Department of Chemistry,Stanford University,Stanford,California 94305-5080,Department of Chemistry,Northwestern University,Evanston,Illinois 60208-3113,Chemical Research Center,Hungarian Academy of Sciences,P.O.Box 17,H-l525 Budapest,Hungary,and Depa;

    Department of Chemistry,Stanford University,Stanford,California 94305-5080,Department of Chemistry,Northwestern University,Evanston,Illinois 60208-3113,Chemical Research Center,Hungarian Academy of Sciences,P.O.Box 17,H-l525 Budapest,Hungary,and Depa;

    Department of Chemistry,Stanford University,Stanford,California 94305-5080,Department of Chemistry,Northwestern University,Evanston,Illinois 60208-3113,Chemical Research Center,Hungarian Academy of Sciences,P.O.Box 17,H-l525 Budapest,Hungary,and Depa;

    Department of Chemistry,Stanford University,Stanford,California 94305-5080,Department of Chemistry,Northwestern University,Evanston,Illinois 60208-3113,Chemical Research Center,Hungarian Academy of Sciences,P.O.Box 17,H-l525 Budapest,Hungary,and Depa;

    Department of Chemistry,Stanford University,Stanford,California 94305-5080,Department of Chemistry,Northwestern University,Evanston,Illinois 60208-3113,Chemical Research Center,Hungarian Academy of Sciences,P.O.Box 17,H-l525 Budapest,Hungary,and Depa;

    Department of Chemistry,Stanford University,Stanford,California 94305-5080,Department of Chemistry,Northwestern University,Evanston,Illinois 60208-3113,Chemical Research Center,Hungarian Academy of Sciences,P.O.Box 17,H-l525 Budapest,Hungary,and Depa;

    Department of Chemistry,Stanford University,Stanford,California 94305-5080,Department of Chemistry,Northwestern University,Evanston,Illinois 60208-3113,Chemical Research Center,Hungarian Academy of Sciences,P.O.Box 17,H-l525 Budapest,Hungary,and Depa;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

  • 入库时间 2022-08-18 03:24:09

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