Neutral Structures with a Planar Tetracoordinated Carbon Based on Spiropentadiene Analogues

摘要

Neutral hydrocarbon structures containing a planar tetracoordinated carbon atom are proposed on the basis of quantum chemical calculations.The planarity at the central carbon atom is achieved by using aromaticity for stabilizing a positively charged core moiety that contains the planar atom.This charge is compensated by negatively charged cyclopentadienyl rings fused on the structure,leading to neutral structures.These are found to be stable from a dynamic point of view and are potentially synthesizable through carbene chemistry.These structures can lead to new breakthroughs in the chemical structure theory.A family of species derived from this model is also presented.