Enantioselective Hydrogenation of Aromatic Ketones Catalyzed by Ru Complexes of Goodwin-Lions-type sp~2N/sp~3N Hybrid Ligands R-BINAN-R'-Py

Hanmin Huang; Masato Kitamura; Masahiro Yoshimura; Kazuomi Tsuda; Tomoko Okuno

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Enantioselective Hydrogenation of Aromatic Ketones Catalyzed by Ru Complexes of Goodwin-Lions-type sp~2N/sp~3N Hybrid Ligands R-BINAN-R'-Py

机译：Goodwin-Lions型sp〜2N / sp〜3N杂配体R-BINAN-R'-Py的Ru配合物催化的芳香酮的对映选择性加氢

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Homogeneous asymmetric hydrogenation of ketones using chiral diphosphine-Ru(II) complexes has been established as one of the most reliable strategies for the synthesis of optically active secondary alcohols since the BINAP-Ru method made its debut in 1987.The invention of BINAP-Ru-diamine-base ternary catalytic systems has further expanded the scope of ketone hydrogenations.

机译：自1987年BINAP-Ru方法问世以来，使用手性二膦-Ru（II）配合物对酮进行均相不对称氢化已成为最可靠的光学活性仲醇合成策略之一。 -二胺基三元催化体系进一步扩大了酮氢化的范围。

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来源
《Journal of the American Chemical Society》 |2006年第27期|p.8716-8717|共2页
作者
Hanmin Huang; Masato Kitamura; Masahiro Yoshimura; Kazuomi Tsuda; Tomoko Okuno;
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作者单位

Research Center for Materials Science and the Department of Chemistry,Nagoya University, Chikusa,Nagoya 464-8602,Japan;

Research Center for Materials Science and the Department of Chemistry,Nagoya University, Chikusa,Nagoya 464-8602,Japan;

Research Center for Materials Science and the Department of Chemistry,Nagoya University, Chikusa,Nagoya 464-8602,Japan;

Research Center for Materials Science and the Department of Chemistry,Nagoya University, Chikusa,Nagoya 464-8602,Japan;

Research Center for Materials Science and the Department of Chemistry,Nagoya University, Chikusa,Nagoya 464-8602,Japan;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类化学;
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1. Mechanism of Asymmetric Hydrogenation of Aromatic Ketones Catalyzed by a Combined System of Ru(π-CH_2C(CH_3)CH_2)_2(cod) and the Chiral sp~2N/sp~3NH Hybrid Linear N4 Ligand Ph-BINAN-H-Py [J] . Hiroshi Nakatsuka, Tomoya Yamamura, Yoshihiro Shuto, Journal of the American Chemical Society . 2015,第25期

机译：Ru（π-CH_2C（CH_3）CH_2）_2（cod）与手性sp〜2N / sp〜3NH杂合线性N4配体Ph-BINAN-H-Py混合体系催化的芳香酮不对称加氢机理
2. Mechanistic Study of the Ru-Catalyzed Asymmetric Hydrogenation of Nonchelatable and Chelatable tert-Alkyl Ketones Using the Linear Tridentate sp(3)P/sp(3)NH/sp(2)N-Combined Ligand PN(H)N: RuNH- and RuNK-Involved Dual Catalytic Cycle [J] . Nakane Satoshi, Yamamura Tomoya, Manna Sudipta Kumar, ACS catalysis . 2018,第12期

机译：使用线性三齿型SP（3）P / SP（3）NH / SP（2）N组合配体PN（H）N：run-and 匝间涉及双催化循环
3. Development of an axially chiral sp(3)P/sp(3)NH/sp(2)N-combined linear tridentate ligand-fac-selective formation of Ru(II) complexes and application to ketone hydrogenation [J] . Yamamura Tomoya, Nakane Satoshi, Nomura Yuko, Tetrahedron . 2016,第26期

机译：轴向手性sp（3）P / sp（3）NH / sp（2）N结合的线性三齿配体-fac选择性Ru（II）配合物的形成及其在酮氢化中的应用
4. Effective Asymmetric Transfer Hydrogenation of Ketones Catalyzed by A New Chiral P-N-P Ligand-Ruthenium Complexes [C] . Yoji Oderaotoshi, Yuki Noguchi, Satoshi Minakata Symposium on Organometallic Chemistry . 2006

机译：新的手性P-N-P配体 - 钌配合物催化的酮催化的有效不对称转移氢化
5. Ruthenium(II)-catalyzed asymmetric transfer hydrogenation of aromatic ketones using new ferrocene-based amino-phosphine ligands featuring planar chirality [D] . Vue, Bao 2008

机译：使用具有平面手性的新型二茂铁基氨基膦配体，钌（II）催化芳族酮的不对称转移氢化
6. cis-Chlorobenzene Dihydrodiol Dehydrogenase (TcbB) from Pseudomonas sp. Strain P51 Expressed in Escherichia coli DH5α(pTCB149) Catalyzes Enantioselective Dehydrogenase Reactions [O] . Henning Raschke, Thomas Fleischmann, Jan Roelof Van Der Meer, 1999

机译：假单胞菌属（Pseudomonas sp。）的顺氯苯二氢二醇脱氢酶（TcbB）。在大肠杆菌DH5α（pTCB149）中表达的P51菌株催化对映选择性脱氢酶反应
7. Enantioselective Hydrogenation of Aromatic Ketones Catalyzed by Ru Complexes of Goodwin-Lions-type sp2N/sp3N Hybrid Ligands R-BINAN-R-Py [O] . -1

机译：Ru复合物催化芳香酮的致注重氢化Guywin-Lions-型Sp2N / SP3N杂交配体R-Binan-R-Py
8. Oxidation State Properties of Delocalized, Ligand-Bridged Metal Complexes. (Ru3O(CH3CO2)6L3)n+ and the Pyrazine-Bridged, Cluster-Cluster Dimer, (Ru3O(CH3CO2)6(py)2)2pyzm+. [R] . Wilson, S. T., Bondurant, R. F., Meyer, T. J., 1975

机译：离域，配体桥联金属配合物的氧化态特性。（Ru 3 O（CH 3 CO 2）6 L 3）n +和吡嗪桥联，簇 - 簇二聚体，（Ru 3 O（CH 3 CO 2）6（py）2）2pyzm +。

Enantioselective Hydrogenation of Aromatic Ketones Catalyzed by Ru Complexes of Goodwin-Lions-type sp~2N/sp~3N Hybrid Ligands R-BINAN-R'-Py

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