Effect of a Tridentate Ligand on the Structure, Electronic Structure, and Reactivity of the Copper(I) Nitrite Complex: Role of the Conserved Three-Histidine Ligand Environment of the Type-2 Copper Site in Copper-Containing Nitrite Reductases

Masato Kujime; Chiemi Izumi; Masaaki Tomura; Masahiko Hada; Hiroshi Fujii

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Effect of a Tridentate Ligand on the Structure, Electronic Structure, and Reactivity of the Copper(I) Nitrite Complex: Role of the Conserved Three-Histidine Ligand Environment of the Type-2 Copper Site in Copper-Containing Nitrite Reductases

机译：三齿配体对亚硝酸铜（I）配合物的结构，电子结构和反应性的影响：2型铜位点的保守三组氨酸配体环境在含铜亚硝酸盐还原酶中的作用

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It is postulated that the copper(l) nitrite complex is a key reaction intermediate of copper containing nitrite reductases (Cu-NiRs), which catalyze the reduction of nitrite to nitric oxide (NO) gas in bacterial denitrification. To investigate the structu

机译：据推测，亚硝酸铜（l）配合物是含铜亚硝酸还原酶（Cu-NiRs）的关键反应中间体，其在细菌反硝化中催化亚硝酸还原为一氧化氮（NO）气体。研究结构

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《Journal of the American Chemical Society》 |2008年第19期|6088-6098|共11页
作者
Masato Kujime; Chiemi Izumi; Masaaki Tomura; Masahiko Hada; Hiroshi Fujii;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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入库时间 2022-08-18 03:19:34

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2. Electronic structural information from Q-band ENDOR on the type 1 and type 2 copper liganding environment in wild-type and mutant forms of copper-containing nitrite reductase [J] . Veselov A., Sienkiewicz A., Shapleigh JP., Biochemistry . 1998,第17期

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Effect of a Tridentate Ligand on the Structure, Electronic Structure, and Reactivity of the Copper(I) Nitrite Complex: Role of the Conserved Three-Histidine Ligand Environment of the Type-2 Copper Site in Copper-Containing Nitrite Reductases

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