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Phosphorus Can Also Be a 'Photocopy'

机译:磷也可以是“影印本”

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摘要

Organophosphorus compounds featuring p-p π bonds between phosphorus and carbon display close similarities to related materials having corresponding carbon-carbon n bonds, and thus, phosphorus has come to be called a "carbon copy". While many properties are mirrored between the two sets of compounds, there remain some that are not reflected when C=C units are replaced by P=C (or P=P) units.
机译:在磷与碳之间具有p-pπ键的有机磷化合物与具有相应的碳-碳n键的相关材料显示出相似的相似性,因此磷已被称为“碳复制”。虽然在两组化合物之间反映了许多特性,但是当C = C单元替换为P = C(或P = P)单元时,仍然存在一些未反映的特性。

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  • 来源
    《Journal of the American Chemical Society》 |2010年第13期|p.4566-4567|共2页
  • 作者单位

    Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106;

    Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106;

    Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106;

    Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106;

    Department of Chemistry and Center for Optical Materials Science and Engineering Technologies (COMSET), Clemson University, Clemson, South Carolina 29634;

    Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106;

    Departments of Chemistry and Physics and the Photon Factory, University of Auckland, Auckland, New Zealand;

    Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106;

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  • 原文格式 PDF
  • 正文语种 eng
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  • 入库时间 2022-08-18 03:15:28

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