Generation of a Carbene-Stabilized Bora-borylene and its Insertion into a C-H Bond

Philipp Bissinger; Holger Braunschweig; Alexander Damme; Rian D. Dewhurst; Thomas Kupfer; Krzysztof Radacki; Katharina Wagner

首页> 外文期刊>Journal of the American Chemical Society >Generation of a Carbene-Stabilized Bora-borylene and its Insertion into a C-H Bond

【24h】

Generation of a Carbene-Stabilized Bora-borylene and its Insertion into a C-H Bond

机译：碳稳定的硼硼烷的生成及其插入到C-H键中

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A novel NHC adduct of a dihalodiborane(4), 1, is reduced by KC_8 with formation of the five-membered boracycle 2. The reaction most likely proceeds via C-H insertion of an intermediate NHC-stabilized free bora-borylene species.

机译：二卤代二硼烷（4）1的新型NHC加合物被KC_8还原，并形成五元硼环2。该反应最有可能通过C-H插入NHC稳定的中间体硼烷-硼烯中空。

著录项

来源
《Journal of the American Chemical Society》 |2011年第47期|p.19044-19047|共4页
作者
Philipp Bissinger; Holger Braunschweig; Alexander Damme; Rian D. Dewhurst; Thomas Kupfer; Krzysztof Radacki; Katharina Wagner;
展开▼
作者单位

Institut fuer Anorganische Chemie, Julius-Maximilians-Universitaet Wuerzburg, Am Hubland, 97074 Wuerzburg, Germany;

Institut fuer Anorganische Chemie, Julius-Maximilians-Universitaet Wuerzburg, Am Hubland, 97074 Wuerzburg, Germany;

Institut fuer Anorganische Chemie, Julius-Maximilians-Universitaet Wuerzburg, Am Hubland, 97074 Wuerzburg, Germany;

Institut fuer Anorganische Chemie, Julius-Maximilians-Universitaet Wuerzburg, Am Hubland, 97074 Wuerzburg, Germany;

Institut fuer Anorganische Chemie, Julius-Maximilians-Universitaet Wuerzburg, Am Hubland, 97074 Wuerzburg, Germany;

Institut fuer Anorganische Chemie, Julius-Maximilians-Universitaet Wuerzburg, Am Hubland, 97074 Wuerzburg, Germany;

Institut fuer Anorganische Chemie, Julius-Maximilians-Universitaet Wuerzburg, Am Hubland, 97074 Wuerzburg, Germany;

展开▼
收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. Reactivity of ortho-β-enaminone-phenyl palladium complexes. Insertion of CO into the Pd-C bond to give the first acyl C,N,O-pincer complexes. sequential insertion of dimethylacetylenedicarboxylate into the enaminone C-H bond and of isocyanide into the Pd-C Bond. A new photooxigenation/cyclization process [J] . Vicente J., Chicote M.T., Martínez-Martínez A.J., Organometallics . 2010,第21期

机译：邻-β-烯胺基-苯基钯配合物的反应性。将CO插入Pd-C键中，得到第一个酰基C，N，O-钳夹配合物。依次将二甲基乙酰二羧酸二甲酯插入到烯胺C-H键中，将异氰化物依次插入Pd-C键中。新的光氧合/环化过程
2. Intermolecular Amidation of Unactivated sp~2 and sp~3 C-H Bonds via Palladium-Catalyzed Cascade C-H Activation/Nitrene Insertion [J] . Hung-Yat Thu, Wing-Yiu Yu, Chi-Ming Che Journal of the American Chemical Society . 2006,第28期

机译：钯催化级联C-H活化/丁二烯插入对未活化的sp〜2和sp〜3 C-H键的分子间酰胺化作用
3. Stepwise Intramolecular Photoisomerization of NHC-Chelate Dimesitylboron Compounds with C-C Bond Formation and C-H Bond Insertion [J] . Ying-Li Rao, Leanne D. Chen, Nicholas J. Mosey, Journal of the American Chemical Society . 2012,第26期

机译：NHC-螯合物二甲磺隆化合物的逐步分子内光异构化，具有C-C键形成和C-H键插入
4. A Computational Study on the Insertion of N(~2D) into a C-H or C-C Bond: The Reactions of N(~2D) with Benzene and Toluene and Their Implications on the Chemistry of Titan [C] . Marzio Rosi, Leonardo Pacifici, Dimitrios Skouteris, International Conference on Computational Science and Its Applications . 2020

机译：将N（〜2D）插入C-H或C-C键的计算研究：N（〜2D）与苯和甲苯的反应及其对泰坦化学的影响
5. Transition metal-mediated reactions of diazo reagents: Cyclopropanation and insertion into benzylic C-H bonds [D] . Hamaker, Christopher G. 1999

机译：过渡金属介导的重氮试剂反应：环丙烷化和插入苄基C-H键
6. Polar molecules catalyze CO insertion into metal-alkyl bonds through the displacement of an agostic C-H bond [O] . Tian Zhou, Santanu Malakar, Steven L. Webb, 2019

机译：极性分子通过取代C-H键来催化CO插入金属-烷基键
7. Transition-Metal-Catalysed Reactions of Diazoesters. Insertion into C-H Bonds of Paraffins Catalysed by Bulky Rhodium(II) Carboxylates: Enhanced Attack on Primary C-H Bonds [O] . A. Demonceau, A. F. Noels, A. J. Hubert, 2010

机译：双重酵母的过渡金属催化反应。插入由粗铑（II）羧酸盐催化的链烷烃的C-H键：对初级C-H键的增强攻击
8. Halomethyl-Metal Compounds. LVII. The Insertion of Phenyl (Bromodichloromethyl)Mercury-Derived Dichlorocarbene into C-H Bonds. Further Studies of the Beta-Metal Activated C-H Insertion Reaction. [R] . Seyferth, D., Cheng, Y. M., Traficante, D. D. 1972

机译：卤甲基金属化合物。 LVII。将苯基（溴二氯甲基）汞衍生的二氯卡宾插入C-H键中。 β-金属活化C-H插入反应的进一步研究。

相关主题

Generation of a Carbene-Stabilized Bora-borylene and its Insertion into a C-H Bond

摘要

著录项

相似文献

相关主题

期刊订阅