Palladium-Catalyzed C-H Aminations of Anilides with N-Fluorobenzenesulfonimide

摘要

The first amide-directed, palladium-catalyzed, intermolecular, highly selective C-H aminations with the non-nitrene-based nitrogen source N-fluorobenzenesulfon-imide have been developed. This methodology might provide a new pathway for directed metal-catalyzed aromatic C-H amination.