A Cubic, 12-Connected, Microporous Metal-Organometallic Phosphate Framework Sustained by Truncated Tetrahedral Nodes

摘要

A rare example of a microporous metal-organic phosphate, [Co_(12)(L)_6(μ_3-PO_4)_4(μ_3-F)_4(μ-H_2O)_6] [NO_3]_ 2 (1), is synthesized by the reaction of a [(η~s-C_5H_5)Fe~Ⅱ]~+-functionalized terephthalate ligand with Co(NO_3)2" 6H_2O and phosphate and fluoride ions generated from the in situ hydrolysis of hexafluorophosphate. 1 is a cubic, 12-connected, face-centered cubic framework sustained by the linear connection of unprecedented, dodecanudear truncated tetrahedral coordination dusters.