Re-Mediated C-C Coupling of Pyridines and Imidazoles

Maialen Espinal Viguri; Miguel A. Huertos; Julio Perez; Lucia Riera; Irene Ara

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Re-Mediated C-C Coupling of Pyridines and Imidazoles

机译：吡啶和咪唑的介导的C-C偶联

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Rhenium tricarbonyl complexes with three AT-heterocyclic ligands (N-alkylimidazoles or pyridines) undergo deprotonation with KN(SiMe_3)_2 and then oxidation with AgOTf to afford complexes with pyridylimidazole or bipyridine bidentate ligands resulting from deprotonation, C-C coupling and rearomatization.

机译：具有三个AT杂环配体（N-烷基咪唑或吡啶）的三羰基hen配合物经过KN（SiMe_3）_2脱质子化处理，然后与AgOTf氧化，得到由吡啶基咪唑或联吡啶二齿配体形成的复合物，这是由于去质子化，C-C偶联和重金属化引起的。

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《Journal of the American Chemical Society》 |2012年第50期|20326-20329|共4页
作者
Maialen Espinal Viguri; Miguel A. Huertos; Julio Perez; Lucia Riera; Irene Ara;
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作者单位

Departamento de Quimica Organica e Inorganica-IUQOEM, Universidad de Oviedo-CSIC, C/Julian Claveria, 8, 33006 Oviedo-Spain;

Departamento de Quimica Organica e Inorganica-IUQOEM, Universidad de Oviedo-CSIC, C/Julian Claveria, 8, 33006 Oviedo-Spain,Department of Chemistry, Inorganic Chemistry Laboratories, South Parks Road, University of Oxford, Oxford, U.K. OX1 3QR;

Departamento de Quimica Organica e Inorganica-IUQOEM, Universidad de Oviedo-CSIC, C/Julian Claveria, 8, 33006 Oviedo-Spain;

Instituto de Sintesis Quimica y Catalisis Homogenea, Departamento de Quimica Inorganica, CSIC-Universidad de Zaragoza,C/Pedro Cerbuna, 12, 50009 Zaragoza, Spain;

Instituto de Sintesis Quimica y Catalisis Homogenea, Departamento de Quimica Inorganica, CSIC-Universidad de Zaragoza,C/Pedro Cerbuna, 12, 50009 Zaragoza, Spain;

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入库时间 2022-08-18 03:13:41

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机译：三羰基complex络合物上的咪唑-腈或咪唑-腈腈C-C偶联

Re-Mediated C-C Coupling of Pyridines and Imidazoles

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