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Simultaneous Determination of Both the Enantiomeric Composition and Concentration of a Chiral Substrate with One Fluorescent Sensor

机译:用一个荧光传感器同时测定手性底物的对映体组成和浓度

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摘要

A fluorescent sensor is discovered to exhibit high sensitivity at one emission wavelength and high enantioselectivity at another when treated with a chiral diamine. By using this fluorescent sensor, it is demonstrated for the first time that both the concentration and enantiomeric composition of a chiral substrate can be determined simultaneously with one fluorescence measurement.
机译:当用手性二胺处理时,发现一种荧光传感器在一个发射波长处显示高灵敏度,而在另一个发射波长处显示高对映选择性。通过使用这种荧光传感器,首次证明了可以通过一次荧光测量同时确定手性底物的浓度和对映体组成。

著录项

  • 来源
    《Journal of the American Chemical Society》 |2012年第50期|20282-20285|共4页
  • 作者单位

    Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, United States;

    Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, United States;

    Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, United States;

    Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, United States;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

  • 入库时间 2022-08-18 03:13:41

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