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A Modular Strategy for Fully Conjugated Donor-Acceptor Block Copolymers

机译：完全共轭的给体-受体嵌段共聚物的模块化策略

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摘要

A novel strategy for the synthesis of fully conjugated donor-acceptor block copolymers, in a single reaction step employing Stille coupling polymerization of end-functional polythiophene and AA + BB monomers, is presented. The unique donor-acceptor structure of these block copolymers provides a rich self-assembly behavior, with the first example of a fully conjugated donor-acceptor block copolymer having two separate crystalline domains being obtained.
机译：提出了在采用端官能聚噻吩和AA + BB单体的斯蒂勒偶联聚合的单个反应步骤中合成完全共轭的供体-受体嵌段共聚物的新策略。这些嵌段共聚物的独特的供体-受体结构提供了丰富的自组装行为，获得了具有两个单独的晶域的完全共轭的供体-受体嵌段共聚物的第一个实例。

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  • 来源
    《Journal of the American Chemical Society》 |2012年第38期|p.16040-16046|共7页
  • 作者

    Sung-Yu Ru; Michael A Brady; Neil D. Treat; Justin E. Cochran; Maxwell J. Robb; Edward J. Kramer; Michael L. Chabinyc; Craig J. Hawker;

  • 作者单位

    Materials Research Laboratory,University of California, Santa Barbara, California 93106,United States,Mitsubishi Chemical Center for Advanced Materials, University of California, Santa Barbara, California 93106,United States;

    Materials Research Laboratory,University of California, Santa Barbara, California 93106,United States,Materials Department,University of California, Santa Barbara, California 93106,United States;

    Materials Research Laboratory,University of California, Santa Barbara, California 93106,United States,Materials Department,University of California, Santa Barbara, California 93106,United States;

    Materials Research Laboratory,University of California, Santa Barbara, California 93106,United States,Department of Chemistry and Biochemistry,University of California, Santa Barbara, California 93106,United States;

    Materials Research Laboratory,University of California, Santa Barbara, California 93106,United States,Department of Chemistry and Biochemistry,University of California, Santa Barbara, California 93106,United States;

    Materials Research Laboratory,University of California, Santa Barbara, California 93106,United States,Materials Department,University of California, Santa Barbara, California 93106,United States,Department of Chemical Engineering,University of California, Santa Barbara, California 93106,United States,Mitsubishi Chemical Center for Advanced Materials, University of California, Santa Barbara, California 93106,United States;

    Materials Research Laboratory,University of California, Santa Barbara, California 93106,United States,Materials Department,University of California, Santa Barbara, California 93106,United States,Mitsubishi Chemical Center for Advanced Materials, University of California, Santa Barbara, California 93106,United States;

    Materials Research Laboratory,University of California, Santa Barbara, California 93106,United States,Materials Department,University of California, Santa Barbara, California 93106,United States,Department of Chemistry and Biochemistry,University of California, Santa Barbara, California 93106,United States,Mitsubishi Chemical Center for Advanced Materials, University of California, Santa Barbara, California 93106,United States;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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  • 正文语种 eng
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  • 入库时间 2022-08-18 03:13:38

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