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首页> 外文期刊>Journal of the American Chemical Society >NH_2-MIL-53(AI): A High-Contrast Reversible Solid-State Nonlinear Optical Switch
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NH_2-MIL-53(AI): A High-Contrast Reversible Solid-State Nonlinear Optical Switch

机译：NH_2-MIL-53（AI）：高对比度可逆固态非线性光学开关

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摘要

The metal-organic framework NH_2-MIL-53 (Al) is the first solid-state material displaying nonlinear optical switching due to a conformational change upon breathing. A switching contrast of at least 38 was observed. This transition originates in the restrained linker mobility in the very narrow pore configuration.
机译：金属有机骨架NH_2-MIL-53（Al）是第一种固态材料，由于呼吸时的构象变化而显示出非线性光学转换。观察到至少38的开关对比度。该转变源自在非常狭窄的孔构型中受限制的接头迁移。

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  • 来源
    《Journal of the American Chemical Society》 |2012年第20期|p.8314-8317|共4页
  • 作者

    Pablo Serra-Crespo; Monique A. van der Veen; Elena Gobechiya; Kristof Houthoofd; Yaroslav Filinchuk; Christine E. A Kirschhock; Johan A. Martens; Bert F. Sels; Dirk E. De Vos; Freek Kapteijn; Jorge Gascon;

  • 作者单位

    Catalysis Engineering, Chemical Engineering Department, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands;

    Centre for Surface Chemistry and Catalysis, Faculty of Bioscience Engineering, University of Leuven, 3001 Leuven, Belgium Molecular Electronics and Photonics, Department of Chemistry, University of Leuven, 3001 Leuven, Belgium;

    Centre for Surface Chemistry and Catalysis, Faculty of Bioscience Engineering, University of Leuven, 3001 Leuven, Belgium;

    Centre for Surface Chemistry and Catalysis, Faculty of Bioscience Engineering, University of Leuven, 3001 Leuven, Belgium;

    Institute of Condensed Matter and Nanosciences, Universite Catholique de Louvain, Place L. Pasteur 1, 1348 Louvain-la-Neuve, Belgium;

    Centre for Surface Chemistry and Catalysis, Faculty of Bioscience Engineering, University of Leuven, 3001 Leuven, Belgium;

    Centre for Surface Chemistry and Catalysis, Faculty of Bioscience Engineering, University of Leuven, 3001 Leuven, Belgium;

    Centre for Surface Chemistry and Catalysis, Faculty of Bioscience Engineering, University of Leuven, 3001 Leuven, Belgium;

    Centre for Surface Chemistry and Catalysis, Faculty of Bioscience Engineering, University of Leuven, 3001 Leuven, Belgium;

    Catalysis Engineering, Chemical Engineering Department, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands;

    Catalysis Engineering, Chemical Engineering Department, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands;

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  • 入库时间 2022-08-18 03:13:28

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