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M_(12)L_(24) Spheres with Endo and Exo Coordination Sites: Scaffolds for Non-Covalent Functionalization

机译:M_(12)L_(24)具有内和外协调位点的球体:用于非共价功能化的支架

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摘要

M_(12)L_(24) spherical complexes incorporating 24 free pyridine rings on their interior or exterior surfaces were synthesized via the self-assembly of tridentate tris(pyridine) ligands with Pd~(2+) ions. Coordination of secondary metal ions in the interior of the spherical framework was achieved through interactions of 24 Ag~+ ions with the free endo pyridine rings.
机译:通过三齿三(吡啶)配体与Pd〜(2+)离子的自组装合成了M_(12)L_(24)球形配合物,在其内表面或外表面结合了24个吡啶环。球形骨架内部二级金属离子的配位是通过24个Ag〜+离子与游离吡啶环的相互作用实现的。

著录项

  • 来源
    《Journal of the American Chemical Society》 |2013年第34期|12497-12499|共3页
  • 作者单位

    Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan;

    Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan;

    Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan;

    Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
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  • 入库时间 2022-08-18 03:12:50

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