Oxygen Transfer from an Intramolecularly Coordinated Diaryltellurium Oxide to Acetonitrile. Formation and Combined AIM and ELI-D Analysis of a Novel Diaryltellurium Acetimidate

Ole Mallow; Jens Bolsinger; Pamela Finke; Malte Hesse; Yu-Sheng Chen; Andrew Duthie; Simon Grabowsky; Peter Luger; Stefan Mebs; Jens Beckmann

首页> 外文期刊>Journal of the American Chemical Society >Oxygen Transfer from an Intramolecularly Coordinated Diaryltellurium Oxide to Acetonitrile. Formation and Combined AIM and ELI-D Analysis of a Novel Diaryltellurium Acetimidate

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Oxygen Transfer from an Intramolecularly Coordinated Diaryltellurium Oxide to Acetonitrile. Formation and Combined AIM and ELI-D Analysis of a Novel Diaryltellurium Acetimidate

机译：氧从分子内配位的二芳基氧化碲转移至乙腈。新型乙酰基二芳基碲的形成以及联合的AIM和ELI-D分析

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The reaction of the intramolecularly coordinated diaryltellurium(Ⅳ) oxide (8-Me_2NC_(10)H_6)_2TeO with acetonitrile proceeds with oxygen transfer and gives rise to the formation of the novel zwitterionic diaryltelluronium(Ⅳ) acetimidate (8-Me_2NC_(10)H_6)_2TeNC(O)CH_3 (1) in 57% yield. Hydrolysis of 1 with hydrochloric acid affords acetamide and the previously known diarylhydroxytelluronium(Ⅳ) chloride [(8-Me_2NC_(10)H_6)_2Te(OH)]Cl.

机译：分子内配位的二芳基二氧化碲（Ⅳ-）（8-Me_2NC_（10）H_6）_2TeO与乙腈的反应随着氧的转移而进行，并形成了新的两性离子二芳基二碲化钌（Ⅳ）乙酰亚胺（8-Me_2NC_（10）H_6 ）_2TeNC（O）CH_3（1），产率为57％。用盐酸水解1得到乙酰胺和先前已知的二芳基羟基碲（Ⅳ）氯化物[（8-Me_2NC_（10）H_6）_2Te（OH）] Cl。

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来源
《Journal of the American Chemical Society》 |2014年第31期|10870-10873|共4页
作者
Ole Mallow; Jens Bolsinger; Pamela Finke; Malte Hesse; Yu-Sheng Chen; Andrew Duthie; Simon Grabowsky; Peter Luger; Stefan Mebs; Jens Beckmann;
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作者单位

Institut fuer Anorganische Chemie, Universitaet Bremen, Leobener Str., 28359 Bremen, Germany;

Institut fuer Chemie und Biochemie, Freie Universitaet Berlin, Fabeckstr. 34/36, 14195 Berlin, Germany;

Institut fuer Anorganische Chemie, Universitaet Bremen, Leobener Str., 28359 Bremen, Germany;

Institut fuer Anorganische Chemie, Universitaet Bremen, Leobener Str., 28359 Bremen, Germany,Institut fuer Chemie und Biochemie, Freie Universitaet Berlin, Fabeckstr. 34/36, 14195 Berlin, Germany;

ChemMatCARS, Center for Advanced Radiation Sources, The University of Chicago, 9700 S. Cass Avenue, Argonne, Illinois 60439,United States;

School of Life and Environmental Sciences, Deakin University, Pigdons Road, Waurn Ponds 3217, Australia;

Institut fuer Chemie und Biochemie, Freie Universitaet Berlin, Fabeckstr. 34/36, 14195 Berlin, Germany,School of Chemistry and Biochemistry, The University of Western Australia, 35 Stirling Highway, Crawley WA 6009, Australia;

Institut fuer Chemie und Biochemie, Freie Universitaet Berlin, Fabeckstr. 34/36, 14195 Berlin, Germany;

Institut fuer Chemie und Biochemie, Freie Universitaet Berlin, Fabeckstr. 34/36, 14195 Berlin, Germany;

Institut fuer Anorganische Chemie, Universitaet Bremen, Leobener Str., 28359 Bremen, Germany,Institut fuer Chemie und Biochemie, Freie Universitaet Berlin, Fabeckstr. 34/36, 14195 Berlin, Germany;

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入库时间 2022-08-18 03:11:08

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2. New series of intramolecularly coordinated diaryltellurium compounds. Rational synthesis of the diarylhydroxytelluronium triflate [(8-Me _2NC _(10)H _6) _2Te(OH)](O _3SCF _3) [J] . Beckmann J., Bolsinger J., Duthie A., Organometallics . 2012,第1期

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Oxygen Transfer from an Intramolecularly Coordinated Diaryltellurium Oxide to Acetonitrile. Formation and Combined AIM and ELI-D Analysis of a Novel Diaryltellurium Acetimidate

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