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Pd(0)-Catalyzed Carbene Insertion into Si-Si and Sn-Sn Bonds

机译：Pd（0）催化将碳插入Si-Si和Sn-Sn键中

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摘要

The first Pd(0)-catalyzed carbene insertion into Si-Si and Sn-Sn bonds has been realized by using N-tosylhydrazones as the carbene precursors. Geminal bis(silane) and geminal bis(stannane) derivatives were obtained in good to excellent yields under mild conditions. Migratory insertion of Pd carbene is supposed to be the key step for the reaction.
机译：通过使用N-甲苯磺酰hydr作为卡宾前体，已经实现了第一个Pd（0）催化的卡宾插入Si-Si和Sn-Sn键。在温和的条件下以良好或优异的产率获得了双组分双（硅烷）和双组分双（锡烷）衍生物。钯卡宾的迁移插入被认为是反应的关键步骤。

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  • 来源
    《Journal of the American Chemical Society》 |2015年第40期|12800-12803|共4页
  • 作者

    Zhenxing Liu; Haocheng Tan; Tianren Fu; Ying Xia; Di Qiu; Yan Zhang; Jianbo Wang;

  • 作者单位

    Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China;

    Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China;

    Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China;

    Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China;

    Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China;

    Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China;

    Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
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  • 入库时间 2022-08-18 03:09:47

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