Study on the Solute–Solvent Interactions Using the Solubility of Asymmetric Metal Complex, CoX2(R-py)2, as a Probe of Interaction

摘要

The solubility of some cobalt(II) chloride and bromide complexes of pyridine bases was determined in 10 inert organic solvents. The measured solubilities were analyzed using two different solvent parameters, i.e., Hildebrand's solubility parameter and Richard's E T(30). These contributions to solubility are interpreted in terms of the asymmetric structure of the probe metal complex.