Anode-supported solid oxide fuel cell with electrophoretic deposition-derived electrolyte operated under single-chamber conditions and a methane–air mixture

摘要

In this study, samaria-doped ceria (Sm_0.2Ce_0.8O_1.9, SDC) thin film is deposited on the Ni-SDC support by employing the electrophoretic deposition technique. Various factors are considered for the deposition of SDC films. The corresponding microstructure of the deposited SDC film is examined and correlated to the electrochemical performance as a single-chamber solid oxide fuel cell (sc-SOFC). It is found that the microstructure of the SDC film mainly relates to the particle size of SDC. After heat treatment, highly dense SDC film is obtained with the deposition condition of 5 g L−1 of the SDC suspension (average grain size of SDC, 248 nm), 60 V as the applied potential, and the deposition time of 1 min (18 μm in thickness). For the Ni-SDC/SDC/SSC cell, an open circuit potential of 0.92 V and peak power density of 155 mW cm−2 can be obtained at the furnace temperature of 500 °C.