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首页> 外文期刊>Journal of the Society of Leather Technologists and Chemists >Tanning Properties of 4-((4,6-Dichloro-1,3,5-Triazin-2-yl) Amino) Benzene Sulfonic Acid
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Tanning Properties of 4-((4,6-Dichloro-1,3,5-Triazin-2-yl) Amino) Benzene Sulfonic Acid

机译:4-((4,6-Dichloro-1,3,5-Triazin-2-yl)Amino)苯磺酸的鞣制特性

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摘要

In this work, a triazine tanning agent of 4-((4,6-dichloro-1,3,5-triazin-2-yl)amino) benzenesulfonic acid (SAT) was prepared with cyanuric chloride and sodium p-aminobenzene sulfonate, its structure was confirmed by FTIR spectroscopy, and its tanning property was investigated. The results indicate that SAT can raise the T-s of tanned skin to around 75 degrees C at the optimised dosage of 3%. The stability of tanned leather was tested by washing with aqueous solution of 10w% urea, 10w% NaCl and 1:1 acetone. The results of washing show that the tanned leather of SAT has excellent stability and there are stable covalent bond interactions between SAT and collagen fibres. Based on the results of washing and the structure characteristics of SAT, a tanning mechanism of SAT was given in which the second Cl and the third Cl on the triazine ring can both react with collagen fibres under mild tanning conditions of 35 degrees C to 45 degrees C.
机译:在这项工作中,用氰尿酰氯和对氨基苯磺酸钠制备了4-((4,6-dichloro-1,3,5-triazin-2-yl)amino)苯磺酸(SAT)的三嗪鞣剂,通过FTIR光谱证实了其结构,并研究了其鞣制性能。结果表明,以3%的最佳剂量,SAT可以使晒黑皮肤的T-s升高至75摄氏度左右。鞣制皮革的稳定性通过用10w%尿素,10w%NaCl和1:1丙酮的水溶液洗涤进行测试。洗涤结果表明,SAT的鞣制皮革具有优异的稳定性,并且SAT与胶原纤维之间存在稳定的共价键相互作用。根据洗涤结果和SAT的结构特征,给出了SAT鞣制机理,其中三嗪环上的第二个Cl和第三个Cl都可以在35摄氏度至45摄氏度的温和鞣制条件下与胶原纤维反应C。

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    Wenzhou Univ Coll Chem & Mat Engn Wenzhou 325035 Zhejiang Peoples R China|Wenzhou Univ Zhejiang Prov Key Lab Leather Engn Wenzhou 325035 Zhejiang Peoples R China;

    Wenzhou Univ Coll Chem & Mat Engn Wenzhou 325035 Zhejiang Peoples R China;

    Wenzhou Univ Coll Chem & Mat Engn Wenzhou 325035 Zhejiang Peoples R China|Zhejiang Reach Green Environm Consultants Co Ltd Wenzhou 325000 Zhejiang Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
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  • 正文语种 eng
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