Hydrogen-bonded complexes of 1,1,1-trichloro-2-methyl-2-propanol with some ethers and ketones

摘要

The interaction by hydrogen bond formation of 1,1,1-trichloro-2-methyl-2-propanol with some ethers and acetone was investigated in CCl_4 by means of IR spectroscopy. Equilibrium constants and enthalpies of complex formation were determined. The dependence of the spectroscopic parameters, equilibrium constants and enthalpies of complex formation on the proton donating and proton accepting power of the interacting carbinol and ether are discussed. The results are compared with those of earlier sudies on the complexes of trimethylcarbinol with kctoncs and ethers.