Comparative Raman study of carbon Nanotubes prepared by D.C.Arc discharge and catalytic methods

摘要

The Raman spectra of carbon nanotubes prepared by catalytic (C-CNT) and d.c. are discharge (D-CNT) methods are reported. A previously unnoticed third-order Raman peak at ca. 4248 cm~1 was observed in the Raman spectrum of D-CNT. The Raman features of D-CNT and C-CNT are similar to those of highly oriented pyrolytic graphite (HOPG) and active carbon, respectively. The data also suggest that the increase in disorder in D-CNT compared with HOPG is due to structural defects in D-CNT.