Effect of KOH concentration and anions on the performance of an Ni-H_2 battery positive plate

摘要

The capacity and voltage behavior of electrochemically impregnated sintered nickel positive plates was examined by galvanostatic charging and discharging in a flooded electrolyte cell. Three different concentrations of potassium hydroxide (KOH) (40%, 31% and 26%) and 31% KOH containing dissolved nitrate, sulfate, or silicate were investigated. The end-of-charge voltage at C/10 charge and at 10℃ showed the following order: 40% KOH > 31 % KOH alone, and in the presence of the anions > 26% KOH. The mid-discharge voltage at C/2 discharge was higher in 26% KOH, almost the same for 31% KOH with and without the added contaminants, and much lower for 40% KOH. The plate capacity was marginally affected by cycling in all cases except for 40% KOH, where the capacity declined after 1000 cycles at 80% depth-of-discharge (DOD). At the end of cycling all the plates tested experienced a weight loss, except in the case of 31% KOH, as a result of active material extrusion. Cyclic voltammetry of miniature electrodes in 31% KOH showed that the cathodic peak potentials are less polarized at -5℃ (compared to 25℃) in the presence and absence of silicate. This indicates a slightly higher voltage during discharge in an Ni-H_2 battery. Furthermore, the features of the current-potential profile were practically unchanged in the presence of silicate.