Electrochemical behaviour of carbon electrodes in some electrolyte solutions

摘要

The electrochemical properties of coke and natural graphite in some electrolyte solutions containing diethylcarbonate (DEC) are studied. It is found that natural graphite exhibits an excellent performance, such as high discharge capacity (370 mAh~(-1) g), when a mixed solvent composed of ethylene carbonate (EC) and DEC is used. The charge/discharge characteristics of the coke electrode are not influenced by the species of the electrolyte solution, but those of the natural graphite electrode are very much influenced by the species of the electrolyte solution. It is confirmed that there are three patterns in the behaviour of the graphite electrode in the electrolyte solutions tested in this investigation. In the first pattern, natural graphite can be charged to C_6Li and then discharged. In the second pattern, the charging and discharging of the natural graphite electrode is impossible and destruction of the natural graphite crystal structure is observed. In the third pattern, lithium is intercalated into the graphite layer but the de-intercalation of lithium does not take place.